Conditioning of gas discharge display device

ABSTRACT

There is disclosed a multiple gas discharge device containing an ionizable gaseous medium, the gaseous medium consisting essentially of neon and about 0.01 to about 10 percent atoms of xenon so as to significantly improve the photon conditioning of the device. In one preferred embodiment the gaseous medium consists essentially of neon and about 0.05 to about 5 percent atoms of xenon, most preferably about 0.05 to about 0.5 percent atoms of xenon. The gaseous medium may contain small beneficial amounts of other gaseous ingredients, such as mercury. Likewise, buffering quantities of helium may be incorporated into the panel with the ionizable medium. In one preferred practice hereof, the device contains at least one charge storage dielectric member, the dielectric charge storage surface being coated with at least one layer of at least one member selected from oxides of lead, aluminum, titanium, zirconium, hafnium, silicon, and Group IIa.

United States Patent Fein et a1.

[ 1 *Sept. 2, 1975 CONDITIONING OF GAS DISCHARGE DISPLAY DEVICE [75] Inventors: Michael E. Fein, Toledo; David C.

Hinson, Whitehouse; Wolfgang W. Bode, Sylvania, all of Ohio [73] Assignee: Owens-Illinois, Inc., Toledo, Ohio Notice: The portion of the term of this patent subsequent to Sept. 2, 1992, has been disclaimed.

[22] Filed: Nov. 2, 1973 [21] Appl. No.: 412,500

Related U.S. Application Data [63] Continuation-impart of Ser. No. 186,480, Oct. 4,

1971, abandoned.

[52] U.S. Cl. 313/226; 313/201; 313/223; 315/169 TV; 340/324 M [51] Int. Cl. H01J 61/16; H01J 65/00 [58] Field of Search 315/169 R, 169 TV; 340/324 M; 313/188, 201, 220, 221, 223, 224, 226

[56] References Cited UNITED STATES PATENTS 3,634,719 l/1972 Ernsthauscn 313/210 Primary ExaminerJames W. Lawrence Assistant Examiner-E. R. LaRoche Attorney, Agent, or FirmDonald Keith Wedding [5 7 ABSTRACT There is disclosed a multiple gas discharge device containing an ionizable gaseous medium, the gaseous medium consisting essentially of neon and about 0.01 to about 10 percent atoms of Xenon so as to significantly improve the photon conditioning of the device. In one preferred embodiment the gaseous medium consists essentially of neon and about 0.05 to about 5 percent atoms of Xenon, most preferably about 0.05 to about 0.5 percent atoms of xenon. The gaseous medium may contain small beneficial amounts of other gaseous ingredients, such as mercury. Likewise, buffering quantities of helium may be incorporated into the panel with the ionizable medium. In one preferred practice hereof, the device contains at least one charge storage dielectric member, the dielectric charge storage surface being coated with at least one layer of at least one member selected from oxides of lead, aluminum, titanium, zirconium, hafnium, silicon, and Group 11a.

11 Claims, 4 Drawing Figures PATENTEUSEP 21 7 3,903,446

SHEET 1 OF 2 CONDITIONING OF GAS DISCHARGE DISPLAY DEVICE RELATED APPLICATION This is a continuation-in-part of copending U.S. Pat. Application Ser. No. 186,480. filed Oct. 4, 1971, now abandoned.

BACKGROUND OF THE INVENTION This invention relates to multiple gas discharge devices, especially multiple gas discharge display/memory panels or units which have an electrical memory and which are capable of producing a visual display or representation of data such as numerals, letters, radardisplays, aircraft displays, binary words, educational displays, etc.

Multiple gas discharge display and/or memory panels of one particular type with which the present invention is concerned are characterized by an ionizable gaseous medium, usually a mixture of at least two gases at an appropriate gas pressure, in a thin gas chamber or space between a pair of opposed dielectric charge storage members which are backed by conductor (electrode) members, the conductor members backing each dielectric member typically being appropriately oriented so as to define a plurality of discrete gas discharge units or cells.

In some prior art panels the discharge cells are additionally defined by surrounding or confining physical structure such as apertures in perforated glass plates and the like so as to by physically isolated relative to other cells. In either case, with or without the confining physical structure, charges (electrons, ions) produced upon ionization of the elemental gas volume of a selected discharge cell, when proper alternating operating potentials are applied to selected conductors thereof, are collected upon the surfaces of the dielectric at specifically defined locations and constitute an electrical field opposing the electrical field which created them so as to terminate the discharge for the remainder of the half cycle and aid in the initiation of a discharge on a succeeding opposite half cycle of applied voltage, such charges as are stored constituting an electrical memory.

Thus, the dielectric layers prevent the passage of substantial conductive current from the conductor members to the gaseous medium and also serve as collecting surfaces for ionized gaseous medium charges (electrons, ions) during the alternate half cycles of the AC. operating potentials, such charges collecting first on one elemental or discrete dielectric surface area and then on an opposing elemental or discrete dielectric surface area on alternate half cycles to constitute an electrical memory.

An example of a panel structure containing nonphysically isolated or open discharge cells is disclosed in U.S. Pat. No. 3,499,167 issued to Theodore C.

Baker, et al. 1

An example of a panel containing physically isolated cells is disclosed in the article by D. L. Bitzer and H. G. Slottow entitled The Plasma Display Panel A Digitally Addressable Display -With Inherent Memory, Proceeding of the Fall Joint Computer Conference, IEEE, San Francisco, Calif, November 1966, pages 541-547. Also reference is. made to U.S. Pat. No. 3,559,190.

In the construction of the panel, a continuous'volume of ionizable gas is confined between a pair of dielectric surfaces backed by conductor arrays typically forming matrix elements. The two conductor arrays may be orthogonally related sets of parallel lines (but any other configuration of conductor arrays may be used). The two arrays define at their intersections a plurality of opposed. pairs of charge storage areas on the surfaces of the dielectric bounding or confining the gas. Thus, for a conductor matrix having H rows and C columns the number of elemental or discrete areas will be twice the number of elemental discharge cells.

In addition, the panel may comprise a so-called monolithic structure in which the conductor arrays are created on a single substrate and wherein two or more arrays are separated from each other and from the gaseous medium by at least one insulating member. In such a device the gas discharge takes place not between two opposing elemental areas on two different substrates, but between two contiguous or adjacent elemental areas on the same substrate; the gas being confined between the substrate and an outer retaining wall.

It is also feasible to have a gas discharge device wherein some of the conductive or electrode members are in direct contact with the gaseous medium and the remaining electrode members are appropriately insulated from such gas, i.e., at least one insulated elec trode.

In addition to the matrix configuration, the conductor arrays may be shaped otherwise. Accordingly, while the preferred conductor arrangement is of the crossed grid type as discussed herein, it is likewise apparent that where a maximal variety of two dimensional display patterns is not necessary, as where specific'standardized visual shapes (e.g., numerals, letters, words, etc.) are to be formed and image resolution is not critical, the conductors may be shaped accordingly (e.g., a segmented digit display).

The gas is selected to produce visible light and invisible radiation which may be used to stimulate a phosphor (if visual display is an objective) and a copious supply of charges (ions and electrons) during discharge.

In the prior art, a wide variety of gases and gas mixtures have been utilized as the gaseous medium in a number of different gas discharge devices. Typical of such gases include pure gases and mixtures of C0; C0 halogens; nitrogen; NI-I oxygen; water vapor; hydrogen; hydrocarbons; P 0 boron fluoride; acid fumes; TiCl air; H 0 vapors of sodium, mercury, thallium, cadmium, rubidium, and cesium; carbon disulfide; H 8; deoxygenated air; phosphorus vapors; C I-I CH naphthalene vapor; anthracene; freon; ethyl alcohol; methylene bromide; heavy hydrogen; electron attaching gases; sulfur hexafluoride; tritium; radioactive gases; and the so-called rare or inert Group VIII gases.

In an open cell Baker, et al. type panel, the gas pressure and the electric field are sufficient to laterally confine charges generated on discharge within elemental or discrete dielectric areas within the perimeter of such areas, especially in a panel containing non-isolated discharge cells. As described in the Baker, et al. patent, the space between the dielectric surfaces occupied by the gas is such as to permit photons generated on discharge in a selected discrete or elemental volume of gas to pass freely through the gas space and strike surface areas of dielectric remote from the selected discrete volumes, such remote, photon struck dielectric surface areas thereby emitting electrons so as to condition at least one elemental volume other than the elemental volume in which the photons originated.

With respect to the memory function of a given discharge panel, the allowable distance or spacing be tween the dielectric surfaces depends, inter alia, on the frequency of the alternating current supply, the distance typically being greater for lower frequencies.

While the prior art does disclose gaseous discharge devices having externally positioned electrodes for initiating a gaseous discharge, sometimes called electrodeless discharge, such prior art devices utilized frequencies and spacing or discharge volumes and operating pressures such that although discharges are initiated in the gaseous medium. such discharges are ineffective or not utilized for charge generation and storage at higher frequencies; although charge storage may be realized at lower frequencies, such charge storage has not been utilized in a display/memory device in the manner of the Bitzer-Slottow or Baker, et al. invention:

The term memory margin is defined herein as where V, is the half-of-peak-to-peak amplitude of the smallest sustaining voltage signal which results in a discharge every half cycle, but at which the cell is not bistable and V is the half amplitude of the minimum applied voltage sufficient to sustain discharge once initiated.

It will be understood that the basic electrical phenomenon utilized in this invention is the generation of charges (ions and electrons) alternately storable at pairs of opposed or facing discrete points or areas on a pair of dielectric surfaces backed by conductors connected to a source of operating potential. Such stored charges result in an electrical field opposing the field produced by the applied potential that created them and hence operate to terminate ionization in the elemental gas volume between opposed or facing discrete points or areas of dielectric surface. The term sustain a discharge means producing a sequence of momentary discharges, at least one discharge for each half cycle of applied alternating sustaining voltage, once the elemental gas volume gas been fired, to maintain alternate storing of charges at pairs of opposed discrete areas on the dielectric surfaces.

As used herein, a cell is in the on state when a quantity of charge is stored in the cell such that on each half cycle of the sustaining voltage, a gaseous discharge is produced.

In addition to the sustaining voltage, other voltages may be utilized to operate the panel, such as firing, addressing, and writing voltages.

A firing voltage is any voltage, regardless of source, required to discharge a cell. Such voltage may be completely external in origin or may be comprised of internal cell wall voltage in combination with externally originated voltages.

An addressing voltage is a voltage produced .on the panel X Y electrode coordinates such that at the selected cell or cells, the total voltage applied across the cell is equal to or greater than the firing voltage whereby the cell is discharged.

A writing voltage is an addressing voltage of sufficient magnitude to make it probable that on subsequent sustaining voltage half cycles, the cell will be in the on state.

In the operation of a multiple gaseous discharge device, of the type described hereinbefore, it is necessary to condition the discrete elemental gas volume of each discharge cell by supplying at least one free electron thereto such that a gaseous discharge can be initiated when the cell is addressed with an appropriate voltage signal.

The prior art has disclosed and practiced various means for conditioning gaseous discharge cells.

One such means of panel conditioning comprises a so-called electronic process whereby an electronic conditioning signal or pulse is periodically applied to all of the panel discharge cells, as disclosed for example in British patent specification No. 1,161,832, page 8, lines 56 to 76. Reference is also made to U.S. Pat. No. 3,559,190 and The Device Characteristics of the Plasma Display Element by Johnson, et al., IEEE Transactions On Electron Devices, September, 1971. However, electronic conditioning is self-conditioning and is only effective after a discharge cell has been previously conditioned; that is, electronic conditioning involves periodically discharging a cell and is therefore a way of maintaining the presence of free electrons. Accordingly, one cannot wait too long between the periodically applied conditioning pulses since there must be at least one free electron present in order to discharge and condition a cell.

Another conditioning method comprises the use of external radiation, such as flooding part or all of the gaseous medium of the panel with ultraviolet radiation. This external conditioning method has the obvious disadvantage that it is not always convenient or possible to provide external radiation to a panel, especially if the panel is in a remote position. Likewise, an external UV source requires auxiliary equipment. Accordingly, the use of internal conditioning is generally preferred.

One internal conditioning means comprises using internal radiation, such as by the inclusion of a radioactive material.

Another means of internal conditioning, which we call photon conditioning, comprises using one or more so-called pilot discharge cells in the on-state for the generation of photons. This is particularly effective in a so-called open cell construction (as described in the Baker, et al. patent) wherein the space between the dielectric surfaces occupied by the gas is such as to permit photons generated on discharge in a selected discrete or elemental volume of gas (discharge cell) to pass freely through the panel gas space so as to condition other and more remote elemental volumes of other discharge units. In addition to or in lieu of the pilot cells, one may use other sources of photons internal to the panel.

Internal photon conditioning may be unreliable when a given discharge unit to be addressed is remote in distance relative to the conditioning source, e.g., the pilot cell. Accordingly, a multiplicity of pilot cells may be required for the conditioning of a panel having a large geometric area. In one highly convenient arrangement, the panel matrix border (perimeter) is comprised of a plurality of such pilot cells.

DRAWINGS ILLUSTRATING GAS DISCHARGE DISPLAY/MEMORY PANEL Reference is made to the accompanying drawings and the hereinafter discussed FIGS. 1 to 4 shown thereon illustrating a gas discharge display/memory panel of the Baker, et a]. type. FIG. 1 is a partially cut-away plan view of a gaseous discharge display/memory panel as connected to a diagrammatically illustrated source of operating potentials.

FIG. 2 is a cross-sectional view (enlarged, but not to proportional scale since the thickness of the gas volume, dielectric members and conductor arrays have been enlarged for purposes of illustration) taken on lines 2 2 of FIG. 1.

FIG. 3 is an exemplary partial cross-sectional view similar to FIG. 2 (enlarged, but not to proportional scale).

FIG. 4 is an isometric view of a gaseous discharge display/memory panel.

The invention utilizes a pair of dielectric films l0 and 11 separated by a thin layer or volume of a gaseous discharge medium 12, the medium 12 producing a copious supply of charges (ions and electrons) which are alternately collectable on the surfaces of the dielectric members at opposed or facing elemental or discrete areas X and Y defined by the conductor matrix on nongas-contacting sides of the dielectric members, each dielectric member presenting large open surface areas, and a plurality of pairs of elemental X and Y areas. While the electrically operative structural members such as the dielectric members and 11 and conductor matrixes 13 and 14 are all relatively thin (being exaggerated in thickness in the drawings) they are formed on and supported by rigid nonconductive support members 16 and 17 respectively.

Preferably, one or both of the nonconductive support members 16 and 17 pass light produced by discharge in the elemental gas volumes. Preferably, they are transparent glass members. These members essentially define the overall thickness and strength of the panel. For example, the thickness of gas layer 12 as determined by spacer 15 is usually under 10 mils and preferably about 3 to 8 mils, dielectric layers 10 and 11 (over the conductors at the elemental or discrete X and Y areas) are usually between 0.] and 2 mils thick, and conductors 13 and 14 at least about 1,000 angstroms thick. However, support members 16 and 17 are much thicker (particularly in larger panels) so as to provide as much ruggedness as may be desired to compensate for stresses in the panel. Support members 16 and 17 also serve as heat sinks for heat generated by discharges and thus minimize the effect of temperature on operation of the device. If it is desired that only the memory function be utilized, then none of the members need be transparent to light.

The electrical properties of support members 16 and 17 are not critical so long as the electrodes are appropriately insulated from one another. The main function of support members 16 and 17 is to provide mechanical support and strength for the entire panel, particularly with respect to pressure differential acting on the panel. Ordinary A inch commercial grade soda lime plate glasses have been used for this purpose. Other glasses such as low expansion glasses or dcvitrified glass can be used provided they can withstand processing.

Spacer 15 may be made of the same glass material as dielectric films l0 and 11 and may be an integral rib formed on one of the dielectric members and fused to the other members to form a bakeable hermetic seal enclosing and confining the ionizable gas volume 12. However, a separate final hermetic seal may be effected by a high strength devitrified glass sealant 15S. Tubulation 18 is provided for exhausting the space between dielectric members 10 and 11 and filling that space with the volume of ionizable gas. For large panels small beadlike solder glass spacers such as shown at 158 may be located between conductor intersections and fused to dielectric members 10 and 11 to aid in withstanding stress on the panel and maintain uniformity of thickness of gas volume 12.

Conductor arrays 13 and 14 may be formed on support members 16 and 17 by a number of well-known processes, such as photoetching, vacuum deposition, stencil screening, etc. In the panel shown in FIG. 4, the center-to-center spacing of conductors in the respective arrays is about 17 mils for one typical commercial configuration. Transparent or semi-transparent conductive material such as tin oxide, gold, or aluminum can be used to form the conductor arrays and should have a resistance less than 3000 ohms per line. Alternately, narrow opaque electrodes may be used so that discharge light passes the edges of the electrodes to reach the viewer. It is important to select a conductor material that is not attacked during processing by the dielectric material.

It will be appreciated that conductor arrays 13 and 14 may be wires or filaments of copper, gold, silver or aluminum or any other conductive metal or material. For example 1 mil wire filaments are commercially available and may be used in the invention. However, formed in situ conductor arrays are preferred since they may be more easily and uniformly placed on and adhered to the support plates 16 and 17.

Dielectric layer members 10 and 11 are formed of an inorganic material and are preferably formed in situ as an adherent film or coating which is not chemically or physically affected during bake-out of the panel. One such material is a solder glass such as Kimble SG-68 manufactured by and commerically available from the assignee of the present invention.

This glass has thermal expansion characteristics substantially matching the thermal expansion characteristics of certain soda-lime glasses, and can be used as the dielectric layer when the support members 16 and 17 are soda-lime glass plates. Dielectric layers 10 and 11 should have dielectric breakdown voltage of about 1000 v. and be electrically homogeneous on a microscopic scale (e.g., no cracks, bubbles, dirt, surface films, etc). In addition, the surfaces of dielectric layers 10 and 1 1 should be good photoemitters of electrons in a baked out condition. Alternately, dielectric layers 10 and 11 may be overcoated with materials designed to produce good electron emission, as in US. Pat. No. 3,634,719, issued to Roger E. Ernsthausen. Of course,

for an optical display at least one of dielectric layers 10 I and 1 1 should pass light generated on discharge and be transparent or translucent and, preferably, both layers are optically transparent.

The preferred spacing between the facing surfaces of the two dielectric films is about 3 to 8 mils if the conductor arrays 13 and 14 have center-to-center spacing of about 17 mils.

The ends of conductors 14-1 14-4 and support members 17 extend beyond the enclosed gas volume 12 and are exposed for the purpose of making electrical connection to interface and addressing circuitry 19. Likewise, the ends of conductors 13-1 13-4 on support member 16 extend beyond the enclosed gas volume 12 and are exposed for the purpose of making electrical connection to interface and addressing circuitry 19.

As in known display systems, the interface and addressing circuitry or system 19 may be relatively inexpensive line scan systems or the somewhat more expensive high speed random access systems. In either case, it is to be noted that a lower amplitude of operating potentials helps to reduce problems associated with the interface circuitry between the addressing system and the display/memory panel, per se. In addition, by providing a panel having greater uniformity in discharge characteristics throughout the panel, manufacturing tolerances of the interfacing ,circuitry can be made less rigid.

One mode of initiating operation of the panel will be described with reference to FIG. 3, which illustrates the condition of one elemental gas volume 30 having an elemental cross-sectional area and volume which is quitesmall relative to the entire volume and cross-sectional area of gas 12. The cross-sectional area of volume 30 is defined by the overlapping common elemental areas of the conductor arrays and the volume is equal to the product of the distance between the dielectric surfaces and the elemental area. It is apparent that if the conductor arrays are uniform and linear and are orthogonally (at right angles to each other) related each of elemental areas X and Y will be squares and if conductors of one conductor array are wider than conductors of the other conductor arrays, said areas will be rectangles. If the conductor arrays are at transverse angles relative to each other, other than 90, the areas will be diamond shaped so that the cross-sectional shape of each volume is determined solely in the first instance by the shape of the common area of overlap between conductors in the conductor arrays 13 and 14. The dotted lines 30' are imaginary lines to show a boundary of one elemental volume about the center of which each elemental discharge takes place. It is known that the cross-sectional area of the discharge in a gas is affected by, inter alia, the pressure of the gas, such that, if desired, the discharge may even be constricted to within an area smaller than the area of conductor overlap. By utilization of this phenomena, the light production may be confined or resolved substantially to the area of the elemental cross-sectional area defined by conductor overlap. Moreover, by operating at such pressure charges (ions and electrons) produced on discharge are laterally confined so as to not materially affect operation of adjacent element discharge volumes.

In the instance shown in FIG. 3, a conditioning discharge about the center of elemental volume 30 has been initiated by application to conductor 13-1 and conductor 14-1 firing potential V as derived from a source 35 of variable phase, for example, and source 36 of sustaining potential V, (which may be a sine wave, for example). The potential V is added to the sustaining potential V, as sustaining potential V, increases in magnitude to initiate the conditioning discharge about the center of elemental volume 30 shown in FIG. 3. There, the phase of the source 35 of potential V, has

been adjusted into adding relation to the alternating voltage from the source 36 of sustaining voltage V to provide a voltage V,, when switch 33 has been closed, to conductors 13-1 and 14-1 defining elementary gas volume 30 'suffficient (in time and/or magnitude) to produce a light generating discharge centered about discrete elemental gas volume 30. At the instant shown, since conductor 13-1 is positive, electrons 32 have collected on and are moving to an elemental area of dielectric member 10 substantially corresponding to the area of elemental gas volume 30 and the less mobile positive ions 31 are beginning to collect on the opposed elemental area of dielectric member 11 since it is negative. As these charges build up, they constitute a back voltage opposed to the voltage applied to conductors 13-1 and 14-1 and serve to terminate the discharge in elemental gas volume 30 for the remainder of a half cycle.

During the discharge about the center of elemental gas volume 30, photons are produced which are free to move or pass through gas medium 12, as indicated by arrows 37, to strike or impact remote surface areas of photoemissive dielectric members 10 and 11, causing such remote areas to release electrons 38. Electrons 38 are created in every other discrete elemental gas volumes, and condition these volumes for operation at a firing potential V, which is lower in magnitude than the firing potential V; for the initial discharge.

Thus, elimination of physical obstructions or barriers between discrete elemental volumes permits photons to travel via the space occupied by the gas medium 12 to remote surface areas of dielectric'members l0 and 11 and provides a mechanism for supplying free electrons to all elemental gas volumes, thereby conditioning all discrete elemental gas volumes for subsequent discharges, respectively, at a substantially uniform lower applied potential. While in FIG. 3 a single elemental volume 30 is shown, it will be appreciated that an entire row (or column) of elemental gas volumes may be maintained in a fired condition during normal operation of the device with the light produced thereby being masked or blocked off from the normal viewing area and not used for display purposes. It can be expected that in some applications there will always be at least one elemental volume in a fired condition and producing light in a panel, and in such applications it is not necessary to provide separate discharge or generation of photons for purposes described earlier.

However, as described earlier, the entire gas volume can be conditioned for operation at uniform firing potentials by use of external or internal radiation so that there will be no need for a separate source of higher potential for initiating an initial discharge. Thus, by irradiating the panel with ultraviolet radiation or by including a radioactive material within the glass materials or gas space, all discharge volumes can be operated at uniform potentials from addressing and interface circuit 19.

Since each discharge is terminated upon a build-up or storage of charges at opposed pairs of elemental areas, the light produced is likewise terminated. In fact, light production lasts for only a small fraction of a half cycle of applied alternating potential and, depending on design parameters, is typically in the submicrosecond range.

After the initial firing or discharge of discrete elemental gas volume 30 by a firing potential V,', switch 33 may be opened so that only the sustaining voltage V from source 36 is applied to conductors 13-1 and 14-1. Due to the storage of charges at the opposed elemental areas X and Y, the elemental gas volume 30 will discharge again at or near the peak of the following half cycle of V, (which is of opposite polarity) to again produce a momentary pulse of light. At this time, due to reversal of field direction, electrons 32 will collect on and be stored on elemental surface area Y of dielectric member 11 and positive ions 31 will collect and be stored on elemental surface area X of dielectric member 10. After a few cycles of sustaining voltage V the times of discharges become symmetrically located with respect to the wave form of sustaining voltage V,,. At remote elemental volumes, as for example, the elemental volumes defined by conductor 14-1 with conductors 13-2 and 13-3, a uniform magnitude or potential V from source 60 is selectively added by one or both of switches 34-2 or 34-3 to the sustaining voltage V shown as 36, to fire one or both of these elemental discharge volumes. Due to the presence of free electrons produced by photons from the discharge centered about elemental volume 30, each of these remote discrete elemental volumes have been conditioned for operation at uniform firing potential V In order to turn off" an elemental gas volume (i.e., terminate a sequence of discharges representing the on state), the sustaining voltage may be removed. However, since this would also turn off other elemental volumes along a row or column, it is preferred that the volumes be selectively turned off by application to selected on elemental volumes a voltage which can neutralize the charges stored at the pairs of opposed elemental areas.

This can be accomplished in a number of ways, as for example, varying the phase or time position of the potential from source 60 to where the voltage combined with the potential from source 36' falls substantially below the sustaining voltage.

It is apparent that the plates 16-17 need not be flat but may be curved, curvature of facing surfaces of each plate being complementary to each other, so that the gap between plates remains substantially uniform over their entire surfaces. While the preferred conductor arrangement is of the crossed grid type as shown herein, it is likewise apparent that where an infinite variety of two dimensional display patterns are not necessary, as where specific standardized visual shapes (e.g., numerals, letters, words, etc.) are to be formed and image resolution is not critical, the conductors may be shaped accordingly. Reference is made to British Patent Specification No. 1,302,148 and U.S. Pat. No. 3,711,733 wherein non-grid electrode arrangements are illustrated.

The device shown in FIG. 4 is a panel having a large (FIG. 3). In this case more room is provided to make electrical connection to the conductor arrays 13' and 14, respectively, by extending the surfaces of support members 16' and 17' beyond seal 15S, alternate conductors being extended on alternate sides. Support members 16 and 17 are typically transparent. The dielectric coatings are not shown in FIG. 4 but are likewise transparent so that the panel may be viewed from either side.

THE INVENTION As described in the Baker, et al. patent, the space between the dielectric surfaces occupied by the gas is such as to permit photons generated on discharge in a selected discrete or elemental volume of gas (discharge unit) to pass freely through the panel gas space so as to condition other and more remote elemental volumes of other discharge units.

However, such internal photon generation and electron conditioning of the panel gaseous medium becomes unreliable when a given discharge unit to be addressed is remote in distance (an inch or more) relative to the conditioning source, e.g., the pilot unit. Thus, a multiplicity of pilot units or cells may be required for the conditioning of a panel having a large geometric area.

This invention comprises an important improvement for the conditioning of a multiple gas discharge device by internal photon generation.

More particularly, in accordance with the practice of this invention, it has been surprisingly discovered that in the operation of a multiple gas discharge device comprising an ionizable gaseous medium wherein a tobe-addressed discharge cell is conditioned by photon radiation emanating from a relatively remote conditioning source, typically a remote discharge site on or near the panel border, the photon conditioning of the device is significantly improved by utilizing an ionizable gaseous medium consisting essentially of neon and about 0.01 to about 10 percent atoms of xenon.

As used herein, the photon conditioning of the device has been improved when there has been a reduction of the write pulse voltage required to address the worst conditioned cell in the device with 100% efficiency.

As used herein, worst conditioned cell is that device cell which receives the lowest photon flux from a relatively remote conditioning source, such as a remote discharge cell on or near the panel border.

In one preferred embodiment hereof, there is used an ionizable gaseous medium consisting essentially of neon and about 0.05 to about 5 percent atoms of xenon.

In one highly preferred embodiment hereof, there is used an ionizable gaseous medium consisting essentially of neon and about 0.05 to about 0.5 percent atoms of xenon.

In addition it is contemplated that the gaseous medium may contain small beneficial amounts of other gaseous ingredients, such as mercury.

Likewise, there may be incorporated into the ionizable gaseous medium a buffering quantity of helium, so as to improve the device operating characteristics and operating life span of the device, e.g., about 5 percent to about percent atoms of helium based on the total quantity of ionizable gaseous medium and incorporated helium.

In one highly preferred embodiment hereof, there is prepared a gas discharge display/memory panel of the Baker, et a1. type utilizing 99.9 percent atoms of neon and 0.1 percent atoms of xenon at 400 Torr, to which there is added 300 Torr of helium.

In one of the most preferred embodiments hereof, there is used as gas discharge display/memory device comprising at least one insulated electrode; that is, at least one dielectric charge storage member.

In the preferred practice of this invention, the charge storage portion of the dielectric is coated with at least one layer of at least one member selected from oxides of lead, aluminum, titanium, zirconium, hafnium, silicon, and Group Ila, typically to a thickness per layer of about 200 angstrom units to about 10,000 angstrom units.

As used herein, the term layer is intended to be all inclusive of other similar terms such as film, deposit, coating, finish, spread, covering, etc., whether continuous or discontinuous.

Group Ila is defined as including the elements Be, Mg, Ca, Sr, and Ba. Likewise, Ra is intended although economics may prohibit common usage.

In one specific embodiment, the dielectric is coated with a phosphor capable of excitation by the ionized gaseous medium. Of all the rare gases, xenon is the most preferred for phosphor excitation.

In another specific embodiment, the dielectric is first coated with a phosphor and is then coated with one or more of the aforementioned layers over the phosphor layer.

In another specific embodiment, the dielectric is coated with a first layer of an oxide of Al, Ti, Zr, I-If, or Si, and a second layer of an oxide of Pb.

In still a further specific embodiment, a triple overcoat is applied to the dielectric, said triple overcoat comprising: a first layer of at least one compound of Group Ila, Al, Ti, Zr, l-If, or Si; a second layer of at least one compound of Group IIA, Al, Ti, Zr, Hf, or Si which is chemically different from the first layer; and a third layer of an electron-emissive material; the combination of the first and second layers being sufficient to prevent ion migration from the dielectric to the third layer and sufficient to provide a thermally and structurally stable base for the third layer; and the second layer being chemically most relative to the third layer.

The combination of the first and second layers should provide a thermally and structurally stable base for the top layer; that is, the first two layers must be such that there is a minimum formation of cracks, fissures, flaws, crazes, crevices, etc., especially during the thermal sealing of the panel.

The three layers are preferably non-conductive. However, conductive materials may be utilized if such are applied in island-like geometric patterns (e.g., at each cell site) so as to be structurally and electrically isolated from the electrodes and/or gaseous medium.

As used herein, electron-emissive refers to the processes of photoemission; secondary electron emission due to bombardment by ions, electrons, excited atoms, or excited molecules; and thermionic electron emission.

Typical conductive or semi-conductive materials which may be utilized, such as in an isolated geometric arrangement, comprises GaAs, GaP, InAs, InSb, InP, NiO, AgOCs, and AuOCs.

Preferably there is used a non-conductive substance such as CsF, CsI, lead oxide, and/or magnesium oxide.

In a specific embodiment of the triple overcoat, each dielectric surface is provided with a first layer of silica, a second layer of aluminum oxide, and a third layer of lead oxide.

In another specific embodiment, there is utilized a first layer of silica, a second layer of zirconium oxide, and a third layer of lead oxide.

A further specific embodiment comprises a first layer of magnesium oxide, a second layer of zirconium oxide, and a third layer of lead oxide.

Still another specific embodiment comprises a first layer of Si N a second layer of silica, and a third layer of lead oxide.

Another embodiment comprises a first layer of magnesium oxide, a second layer of aluminum oxide, and a third layer of lead oxide.

Another embodiment comprises a first layer of silica, a second layer of aluminum oxide, and a third layer of magnesium oxide.

Another embodiment comprises a first layer of silica, a second layer of zirconium oxide, and a third layer of magnesium oxide.

Another embodiment comprises a first layer of magnesium oxide, a second layer of zirconium oxide, and a third layer of magnesium oxide.

Another embodiment comprises a first layer of Si N a second layer of silica, and a third layer of magnesium oxide.

Another embodiment comprises a first layer of magnesium oxide, a second layer of aluminum oxide, and a third layer of magnesium oxide.

Each overcoat layer is applied to the dielectric surface (or previously applied layer) by any convenient means including not by way of limitation vapor deposition; vacuum deposition; chemical vapor deposition; wet spraying upon the surface a mixture or solution of the layer substance suspended or dissolved in a liquid followed by evaporation of the liquid; dry spraying of the layer upon the surface; electron beam evaporation; plasma flame and/or arc spraying and/or deposition; and sputtering target techniques.

In the operation of a multiple gas discharge display/- memory device which contains opposing electrode arrays, the writing or addressing of a particular unit or cell is usually effected by applying an addressing voltage to one electrode of the cell and a similar addressing voltage to the opposing electrode of the cell, the phase of such addressing voltage being such that the two ad dresing voltages are algebraically added, for example as disclosed and claimed in copending US. Pat. Application Ser. No. 699,170, filed Jan. 19, 1968, by William E. Johnson and Larry J. Schmersal, and also assigned to the assignee of the instant application.

Since the addressing voltages are derived from the same source, each is equal to the other in magnitude with each therefore representing one-half of the total addressing voltage for the cell.

Furthermore, each opposing electrode of the cell typically serves as an electrode for other cells, especially in an x-y electrode matrix arrangement. In such a ma trix arrangement, an addressing voltage is applied to one x-axis electrode and a similar addressing voltage is applied to a y-axis electrode, the two addressing voltages being algebraically combined across the cell formed by the intersection of the x-axis electrode and the y-axis electrode. Thus the selection of a particular cell to be addressed is effected by the application of addressing voltages to the proper x and y electrodes, e.g., as determined by the appropriate electronic circuitry hardware.

When a particular x or y electrode is addressed, the applied addressing voltage may be sufficient to turnon or fire a particular cell site even though a corresponding addressing voltage is not applied to the opposing electrode of that particular cell site; that is, when addressing voltages are applied to the opposing electrodes of a selected cell, the voltage applied to either electrode may be sufiicient to address other cells (not intended to be addressed). Thus because of nonuniformities in the panel construction, manufacture, etc., one or more cells may be addressable by only one electrode.

In other words, one-half of the total addressing voltage for a to-be-addressed cell will inherently be applied to other not'to-be-addressed cells having a locus along the xelectrode and other not-to-be-addressed cells having a locus along the y-electrode, such one-half of the total addressing voltage being sufficient to tumon one or more of the not-to-be-addressed cells. This phenomenon is defined as half-select. It has been discovered that the practice of this invention substantially improves a particular panels resistance to half-select.

We claim:

1. A gas discharge display/memory device comprising in combination, a pair of spaced-apart nonconductive support members, a pair of conductor arrays arranged one on each of the confronting surfaces of said support members, the arrays being in transverse relative orientation so as to provide a series of crosspoints therebetween, each defining a discharge unit, a thin dielectric material coating on the confronting surfaces of each of the support members and conductor arrays defining therebetween a sealed gas chamber with said discharge units in open photonic communication, and an ionizable gaseous medium contained in said chamber, said dielectric material coating being adapted to insulate said conductor arrays from said ionizable gaseous medium contained in said chamber and for storing charges emitted by gaseous discharge and said ionizable gaseous medium consisting essentially of neon and about 0.01 to about percent atoms of xenon so as to significantly improve the photon conditioning of the device.

2. The invention of claim 1 wherein the gaseous medium consists essentially of neon and about 0.05 to about 5 percent atoms of xenon.

3. The invention of claim 1 wherein the gaseous medium consists essentially of neon and about 0.05 to about 0.5 percent atoms of xenon.

4. The invention of claim 1 wherein there-is incorporated into the gaseous medium a buffering quantity of helium.

5. The invention of claim 1 wherein the charge storage portion of each dielectric member includes a coating containing at least one member selected from the group consisting of oxides of lead, aluminum, titanium, zironium, hafnium, silicon and Group HA.

6. In a gaseous discharge display/memory device comprising an ionizable gaseous medium in a gas chamber formed by a pair of opposed dielectric material charge storage members backed by electrode members, the electrode members behind each dielectric material member being transversely oriented with respect to the electrode members behind the opposing dielectric material member so as to define a plurality of discharge units, the improvement wherein the gaseous medium consists essentially of neon and about 0.01 to about 10 percent atoms of xenon so as to significantly improve the photon conditioning of the device.

7. The invention of claim 6 wherein the gaseous medium consists essentially of neon and about 0.05 to about 5 percent atoms of xenon.

8. The invention of claim 6 wherein the gaseous medium consists essentially of neon and about 0.05 to about 0.05 percent atoms of xenon.

9. In a process for the manufacture of a gaseous discharge display/memory device wherein a gas chamber is formed by assembling a pair of opposed dielectric material charge storage members in spaced and sealed relationship and electrode members behind each dielectric material charge storage member, the electrode members behind one dielectric material being transversely oriented with respect to the electrode members behind the opposing dielectric material so as to define a plurality of discharge units, the improvement which comprises filling the gas chamber with an ionizable gaseous medium consisting essentially of neon and about 0.01 to about 10 percent atoms of xenon so as to significantly improve the photon conditioning of the device.

10. The invention of claim 9 wherein the gaseous medium has incorporated therein a buffering quantity of helium.

11. The invention of claim 10 wherein the gaseous medium consists essentially of neon and about 0.05 to about 0.5 percent atoms of xenon. 

1. A GAS DISCHARGE DISPLAY/MEMORY DEVICE COMPRISING IN COMBINATION, A PAIR OF SPACED-APART NON-CONDUCTIVE UPPORT MEMBERS, A PAIR OF CONDUCTOR ARRAYS ARAANGED ONE ON EACH OF THE CONFRONTING SURFACE OF SAID SUPPORT MEMBERS, THE ARRAYS BEING IN TRANSVERSE RELATIVE ORINATATION SO AS TO PROVIDE A SERIES OF CROSS-POINTS THEREBETWEEN, EACH DEFINING A DISCHARGE UNIT, A THIN DIELECTRIC MATERIAL COATING ON THE CONFRONTING SURFACES OF EACH OF THE SUPPORT MEMBERS AND CONDUCTOR ARRAYS DEFINING THEREBETWEEN A SEALED GAS CHAMBER WITH SAID DISCHARGE UNITS IN OPEN PHOTONIC COMMUNICATION, AND AN IONIZABLE GASEOUS MEDIUM CONTAINED IN SAID CHAMBER, SAID DIELECTRIC MATERIAL COATING BEING ADAPTED TO INSULATE SAID CONDUCTOR ARRAYS FROM SAID IONIZABLE GASEOUS MEDIUM CONTAINED IN SAID CHAMBER AND FOR STORING CHARGES EMITTED BY GASEOUS DISCHARGE AND SAID IONIZABLE GASEOUS MEDIUM CONSISTING ESSENTIALLY OF NEON AND ABOUT 0.01 TO ABOUT 10 PERCENT ATOMS OF XENON SO AS TO SIGNIFICANTLY IMPROVE THE PHOTON CONDITIONING OF THE DEVICE.
 2. The invention of claim 1 wherein the gaseous medium consists essentially of neon and about 0.05 to about 5 percent atoms of xenon.
 3. The invention of claim 1 wherein the gaseous medium consists essentially of neon and about 0.05 to about 0.5 percent atoms of xenon.
 4. The invention of claim 1 wherein there is incorporated into the gaseous medium a buffering quantity of helium.
 5. The invention of claim 1 wherein the charge storage portion of each dielectric member includes a coating containing at least one member selected from the group consisting of oxides of lead, aluminum, titanium, zironium, hafnium, silicon and Group IIA.
 6. In a gaseous discharge display/memory device comprising an ionizable gaseous medium in a gas chamber formed by a pair of opposed dielectric material charge storage members backed by electrode members, the electrode members behind each dielectric material member being transversely oriented with respect to the electrode members behind the opposing dielectric material member so as to define a plurality of discharge units, the improvement wherein the gaseous medium consists essentially of neon and about 0.01 to about 10 percent atoms of xenon so as to significantly improve the photon conditioning of the device.
 7. The invention of claim 6 wherein the gaseous medium consists essentially of neon and about 0.05 to about 5 percent atoms of xenon.
 8. The invention of claim 6 wherein the gaseous medium consists essentially of neon and about 0.05 to about 0.05 percent atoms of xenon.
 9. In a process for the manufacture of a gaseous discharge display/memory device wherein a gas chamber is formed by assembling a pair of opposed dielectric material charge storage members in spaced and sealed relationship and electrode members behind each dielectric material charge storage member, the electrode members behind one dielectric material being transversely oriented with respect to the electrode members behind the opposing dielectric material so as to define a plurality of discharge units, the improvement which comprises filling the gas chamber with an ionizable gaseous medium consisting essentially of neon and about 0.01 to about 10 percent atoms of xenon so as to significantly improve the photon conditioning of the device.
 10. The invention of claim 9 wherein the gaseous medium has incorporated therein a buffering quantity of helium.
 11. The invention of claim 10 wherein the gaseous medium consists essentially of neon and about 0.05 to about 0.5 percent atoms of xenon. 